The future of MOFs, metal-organic framework materials, looks bright. A review in the International Journal of Environment and Waste Management has looked at how a specific class of these sponge-like materials might find increasing use in removing dye contaminants from industrial wastewater.
Irvan Dahlan and Hamidi Abdul Aziz of the Universiti Sains Malaysia in Pulau Pinang, Malaysia, and Yung-Tse Hung of Cleveland State University in Cleveland, Ohio, USA, have focused on MOF-5 materials. These substances, constructed from a metal such as zinc to which organic molecules are bonds to build vast crystalline structures are highly porous and so have a large internal surface area compared to their overall volume, which means they can soak up, or adsorb (sic) small molecules, such as organic dye pollutants present in industrial wastewater.
The textile, pharmaceutical, and paper industries all generate vast quantities of wastewater contaminated with synthetic dyes. This represents an enormous burden on the environment and a serious risk to ecosystems where this contaminated wastewater might end up.
Organic dyes can be stubborn pollutants, as they are often chemically stable and difficult to break down. They can resist traditional wastewater treatments. Once present in natural waters, they block sunlight and so hamper photosynthesis in aquatic plants, and can thus disturb entire ecosystems. Moreover, some dyes are toxic, carcinogenic, or have mutagenic properties, and so represent a risk to marine life as well as throwing up health concerns for communities dependent on the water sources that are contaminated.
Conventional dye-removal methods, such as chemical treatment, filtration, and biological processes, are often too costly and complex to be commercially viable and commonly inefficient at handling large volumes of wastewater regardless of cost. MOFs, on the other hand, have emerged as a promising alternative due to their unique structures. Importantly, simple changes to the organic molecules from which they are constructed, and the metals used to lock these molecules together into a three-dimensional structure can be made relatively easily so that they can be given different pore sizes and adsorption characteristics.
The team’s review shows that much work remains to be done with MOF-5 materials so that they bugger pore sizes can be developed for the larger dye molecules. There is also a need to improve the durability and reusability of these materials to make them suitable for industrial remediation use. Optimisation of their physical and chemical characteristics is now possible, but there is also a need to find ways to scale up their manufacture economically.
Dahlan, I., Aziz, H.A. and Hung, Y-T. (2024) ‘Recent development of metal-organic framework 5 adsorbents for organic dye removal from aqueous solution’, Int. J. Environment and Waste Management, Vol. 35, No. 3, pp.378–389.