Periodic table trends

The Periodic Table of the Chemical Elements is an ultimate and fundamental of nature or merely a tool for creating useful patterns in chemistry. Discuss.

It could be a critical essay title from an undergraduate course in the philosophy of chemistry but it isn’t, it’s a real life periodic debate that rages on year after year among chemists who hope to find an ultimate form for the Periodic Table and those who suggest that any form will do as long as it is useful iin education and research. I recently published a summary of the state of the art regarding such forms and the stance of those who see them as nothing more than aesthetic variations on the theme and those who regard them as taking us a step closer to such an ultimate form for the Table. You can read the periodic debate over how the Table is complete, but not finished in my June Research Highlight column on Chemistry Views. A more in-depth version of the article in which UCLA’s Eric Scerri offers up a radically different PT and in which Martyn Poliakoff of Periodic Table of Videos fame rebuts the notion that such efforts are taking us closer to the ideal Periodic Table.

The aesthetics and ethics of elemental periodicity

It seems that the Periodic Table is in trouble. Well, not trouble exactly but aside from revisions to the atomic weights announced recently and the official adding to the Table of two “new” elements, 114 and 116, the poetically named and fleeting ununquadium and ununhexium, there is a debate bubbling like a reflux condenser about what precisely the Periodic Table is and what form it should take.

For decades chemistry educators and laboratory technicians have sat back and watched the corners of their good-old Periodic Table wall charts curl, each element in its box, trapped forever, with no alchemical chance to move. But that might soon change. Of course, there have been lots of attempts to rebuild the periodic table over the past 150 years. For instance, there are those, such as museum exhibit designer Roy Alexander, who suggests that in the twenty-first century, the 2D is not to be, and that it is high time that chemists made the switch to a 3D format for the Periodic Table. After all, if it’s good enough for Hollywood and Wimbledon, it should be good enough for chemists.

Spiralling into control

There are those who have attempted to create intriguing spiral Periodic Tables, circular efforts and even fractal charts. One Table dating back to the 1930s considers the sub-atomic particle, the neutron, as itself a element and lists the noble gases twice. In the 1920s Charles Janet built a stepped Periodic Table, which was much wider than the standard PT and would inevitably have been less than convenient for textbook publishers and wall chart printers alike.

Others suggest that subtle rearrangements of various elements would make the Periodic Table more intuitive and circumvent various discrepancies that have arisen as nuclear understanding evolved. Chemical philosopher Eric Scerri of the University of California Los Angeles is among that number. He is devising an alternative approach to elemental organization, which he suggests takes us closer to an ultimate version of the PT. Scerri’s argument for change is based on the fact that Periodic Table arose from the discovery of triads of atomic weights, but he thinks chemists would be better served if they were to recognize the fundamental importance of triads of atomic number instead. His new Periodic Table takes this phenomenon into account.

Scerri stuff indeed

The revision of the Periodic Table to this Scerri form is perhaps especially pertinent given that atomic mass varies according to isotope ratio (neutron count, in other words), whereas atomic number (proton count) is fixed for each element. In it, listings of electron shells follow an ordered pattern, so that the halogens form the first column on the left, topped by hydrogen, the noble gases are the second column, topped by helium. The alkali metals and the alkaline earth metals follow, then the block of transition metals. The semi-metals and the non-metals then form the final four columns. As if this restructuring of the groups were not controversial enough, it is the logical placements of hydrogen and helium that stirs chemical emotions. In relocating H and He, Scerri recreates the atomic number triads of He-Ne-Ar and H-F-Cl; these are not visible in the conventional PT.

However, not everyone is convinced by helium’s placement. Among them is American chemist Henry Bent, known for “Bent’s Rule” of molecular orbitals used by organic chemists and variously written as: “atomic ‘s’ character tends to concentrate in orbitals that are directed toward electropositive groups and atomic p character tends to concentrate in orbitals that are directed toward electronegative groups.” Bent would prefer to see helium atop beryllium in the otherwise “normal” PT layout. He argues that although helium seems to fit perfectly at the top of the noble gases its presence there breaks several of the rules. For instance, a Periodic Group’s first member is never the member of a primary (vertical) triad. This rule holds for 30 of the 32 Groups when He is above Ne. The two exceptions are He-Ne-Ar and Be-Mg-Ca. Move He above Be and the rule now holds for all 32 Groups.

Getting the He-Be-gee-bees

The He-Be debate is something of an aside to the philosophical debate that Scerri has unleashed by being quite so adamant that all the various Periodic Table arrangements are moving towards an ultimate version. He doesn’t wish to imply that his version is the essential, final version of which he speaks, but it is perhaps a step closer than the conventional PT we all know and love. “My belief is that there is one true and objective periodic classification even if we have not yet arrived at it,” he says.

Others, such as Philip Stewart, a longstanding fan of the spiral Periodic Table painted by artist Edgar Longman for the Science Exhibition of the 1951 Festival of Britain, based on chemist John Drury Clark’s 1933 original, is not convinced. Stewart argues that to search for “The Ideal Periodic Representation” is to take leave of the messy world of everyday bodies and drift off into Platonic mysticism. Software developer Melinda Green who developed a fractal Periodic Table for educational use agrees and says that an ultimate PT does not exist. Our perspective inevitably distorts reality, she says, any arrangement is purely subjective. “Neither the periodicity nor any classification is intrinsic to nature,” explains Green. “Periods of what? Where do these classes come from? They come from us to suit our particular purposes,” she says.

Atomic number is perhaps the only intrinsic property of the elements, as suggested by Scerri too, but, adds Green, this is only fundamental by our subjective definition of the term “element” rather than it representing something ultimate about the universe as Scerri’s reasoning would suggest. “I don’t believe that there are any ways to describe anything about the universe without a relative position from which to describe,” adds Green. “Every description requires a describer. Subjectivity is not just an annoyance, it is the source of all meaning.”

Chemistry’s rich pageant

Stewart suggests that we should think of the rich variety of images that have been proposed in the last 150 years as “something more like an art exhibition than a competition to achieve perfection. So, is the elemental menagerie, nothing more than an art gallery? Martyn Poliakoff thinks so. Poliakoff is a professor of chemistry at the University of Nottingham, England, who works on supercritical fluids but has gained fame recently for his involvement in a science engagement project known as the Periodic Table of Videos that has gone “viral” on the internet. Poliakoff takes an entirely pragmatic approach to the PT. “I regard the PT as a tool like a hammer and, just like other tools, you have different forms for different purposes (e.g. a claw-hammer and a mallet). There just isn’t a “right” and “wrong” form. The different forms highlight different aspects,” he says. He suggests that the different forms can be useful, however. “I think that these weird forms of the PT often serve a purpose by highlighting some aspect of the elements that one might not otherwise have noticed,” he says.

However, Scerri is convinced that there is something more fundamental to the ultimate PT. “It concerns me that scientists can express ‘relativistic’ [aesthetic] views on something as important as the Periodic Table,” he says. “It is, after all, the most basic, profound and deep classification that has ever been discovered.” The way we perceive the elements and their relationships with each other is fundamental to understanding matter, Scerri believes. The elements are natural entities, they are not building blocks we have constructed for our convenience. The patterns they obey follow objective rules, laws if you will, that are not decided by us and so do not succumb to the whim of the designers of novel Periodic Tables, stepped, 2D, 3D, spiral, fractal or otherwise.

Practical conclusion

Ever the pragmatist, Poliakoff points out a fact of periodic life that may be inescapable in efforts to raise the Periodic Table to some higher position in science. “In the end, I think that one should remember that Mendeleev devised the Periodict Table for a textbook to help rationalize the mass of facts in inorganic chemistry and to make them easier to teach,” he says. “For me, the PT remains just that, a tool to help reduce the complexity, not a metaphysical truth that has a correct form, as yet to be discovered.”

  • Scerri stuff indeed (sciencebase.com)
  • Two new elements officially added to periodic table (theglobeandmail.com)

Black hole

The European Southern Observatory’s Very Large Telescope (VLT) has helped an international team of astronomers to detect a stellar mass black hole that lies at a much greater distance from Earth than any observed before. The black hole is in the spiral galaxy NGC 300, about six million light years away in the constellation Sculptor.

The spiral galaxy NGC 300 lying in the constellation Sculptor (Credit: Galex/NASA)
The spiral galaxy NGC 300 lying in the constellation Sculptor (Credit: Galex/NASA)

Paul Crowther and Vik Dhillon, of the University of Sheffield, UK, Robin Barnard and Simon Clark of the The Open University, Milton Keynes, UK, and Stefania Carpano and Andy Pollock of ESAC, in Madrid, Spain report the black hole which has a mass of about twenty times that of the Sun in the Monthly Notices of the Royal Astronomical Society.

The stellar-mass black holes found in our Milky Way galaxy commonly weigh up to ten times the mass of the Sun. The newly discovered black hole is not only the most distant, but the second most massive stellar-mass black hole ever found. It is also entwined with a star that will soon become a black hole itself.

Lead author Crowther, explains: “This is the most distant stellar-mass black hole ever weighed, and it’s the first one we’ve seen outside our own galactic neighbourhood, the Local Group. The black hole’s curious partner is a Wolf-Rayet star, which also has a mass of about twenty times as much as the Sun. Wolf-Rayet stars are near the end of their lives and expel most of their outer layers into their surroundings before exploding as supernovae, with their cores imploding to form black holes.

An artist's impression of the newly discovered black hole and its stellar companion (Credit: ESO/L. Calçada)
An artist's impression of the newly discovered black hole and its stellar companion (Credit: ESO/L. Calçada)

In less than a million years, a blink of the eye cosmologically speaking, the Wolf-Rayet star will explode as a supernova and its remnants collapse into a black hole. Only one other system of this type has previously been seen, but other systems comprising a black hole and a companion star are not unknown to astronomy. The existence of such systems hints at an underlying galactic chemistry. Astronomers believe that a higher concentration of heavy chemical elements influences how a massive star evolves, increasing how much matter it sheds, resulting in a smaller black hole when the remnant finally collapses.

LINKS

Monthly Notices Royal Astronom Soc, 2010, in press
http://www.eso.org/public/archives/releases/sciencepapers/eso1004/eso1004.pdf

Paul Crowther
http://pacrowther.staff.shef.ac.uk/main.html

Extracting the H2

US chemists have developed a novel class of materials that are porous and structured like a honeycomb. They have demonstrated that the materials can effectively separate hydrogen from a complex mixture of gases, including carbon dioxide and methane. This property could make them useful as extraction materials for sourcing the feedstock for fuel cells on which the hydrogen economy will be based.

Alternative energy sources, including solar, wind, geothermal power, biofuels, and biomass, are now being actively pursued in the quest to remediate damage to the climate caused by our use of fossil fuels. One other alternative energy supply lies in exploiting the cleanest, and most abundant, chemical fuel of all, hydrogen. Hydrogen burns to release nothing but energy and water as a waste product. It can also be as the chemical power supply for a type of electrical battery known as a fuel cell that again produces no waste but water.

Honeycomb hydrogen filter (Credit: Kanatzidis et al)

Honeycomb hydrogen filter (Credit: Kanatzidis et al)

However, hydrogen is not commonly found in pure form and to extract it from water, the reverse process carried out in a fuel cell would require an alternative, non-fossil fuel energy source of its own. Extracting hydrogen from mixed gas supplies, at oilfields and other sources, is possible but also requires larges amounts of energy.

It seems that, ironically, producing this potentially cleanest of fuels would anything but efficient. Northwestern University chemist Mercouri Kanatzidis, working with postdoctoral research associate Gerasimos Armatas, now at the University of Crete, Greece, have developed a class of porous materials based on the heavy elements germanium, lead and tellurium, that are the best yet for separating hydrogen from carbon dioxide and methane, according to the researchers.

Mercouri Kanatzidis (Credit: Kanatzidis website)

Mercouri Kanatzidis (Credit: Kanatzidis website)

A more selective process means fewer cycles to produce pure hydrogen, increasing efficiency, explains Kanatzidis. Our materials could be used very effectively as membranes for gas separation. We have demonstrated their superior performance.

The materials invented by Kanatzidis and Armatas do not distinguish between gas molecules on the basis of size, as previous separation processes did. Instead they exploit polarization, the interaction of the gas molecules with the walls of the material as the molecules move through a membrane composed of the chemical honeycomb.

Their preliminary tests showed these novel materials to be about four times better at separating hydrogen than other separation materials. Moreover, they work at low temperatures from 0 Celsius to room temperature, meaning they do not need to be heated, or cooled for that matter, to function optimally.

We are taking advantage of what we call ‘soft’ atoms, which form the membrane’s walls, explains Kanatzidis. These soft-wall atoms like to interact with other soft molecules passing by, slowing them down as they pass through the membrane. Hydrogen, the smallest element, is a ‘hard’ molecule. It zips right through while softer molecules, like carbon dioxide and methane take more time.

I am not sure about when these materials will become a commercial reality, Kanatzidis revealed to Intute Spotlight. We are now working to see if we can find even better systems. We want to replace the germanium with something cheaper because it is expensive.

As far as the concept of a hydrogen economy is concerned, that is far into the future because we need to make cheap hydrogen and not from cracking natural gas or coal, Kanatzidis adds. If we succeed in getting hydrogen gas by splitting water using solar energy or nuclear, we may then talk about the hydrogen economy, he told us.

Further reading

Nature Mater., 2009, 8, 217-222
http://dx.doi.org/10.1038/nmat2381

Mercouri Kantzidis research group homepage
http://chemgroups.northwestern.edu/kanatzidis/

Suggested searches

hydrogen
fuel cells